Case Study on Processing of Core Components of Solid Oxide Fuel Cells Based on Ceramic Additive Manufacturing

This case demonstrates the use of ceramic additive manufacturing (3D printing) technology to break through and solve the complex processing problems of the core components of solid oxide fuel cells - the ceramic electrolyte separator and the anode support. It successfully achieved high-performance and complex thin-walled ceramic structures that could not be produced by traditional methods, significantly improving the efficiency and reliability of the battery.

Challenge

To manufacture complex ceramic electrochemical structures with high efficiency and reliability

Complexity challenge of structure: The ideal electrolyte separator needs to be fabricated into an extremely thin (less than 20 micrometers) and large-area complex three-dimensional structure (such as a wavy shape). Traditional molding processes are difficult to achieve and prone to cracking and deformation.

Challenge of material and performance integration: The porous anode support needs to be perfectly co-fired with the dense electrolyte layer. In traditional processes, differences in shrinkage rates often lead to delamination or cracks.

Manufacturing accuracy and consistency challenges: Large-scale production demands extremely high precision in component dimensions and consistency in microstructure. Traditional methods are unable to meet the commercial cost and quality requirements.

Solution

Employing the direct writing molding additive manufacturing technology using ceramic pastes

Integrated free-forming: Using a specific ceramic slurry asink , it is printed layer by layer through a precise print head to directly form an integrated, seamless, and complex thin-walled composite structure, breaking free from the limitations of molds.

Precise control of microstructure: By adjusting the printing parameters, a gradient pore structure of the anode can be simultaneously fabricated, and the heterogeneous materials of the dense layer and the porous layer can be integrated through printing.

Digitalization and Process Control: Full digital manufacturing ensures precise reproduction of designs and high consistency across batches, while combined with online monitoring, it guarantees print quality.

Result

Achieving a breakthrough in the manufacturing of next-generation high-performance solid oxide fuel cells

Significant performance improvement: A large-area, corrugated electrolyte film with a thickness of only 15 micrometers was successfully manufactured, reducing the operating temperature of the battery by 100-150°C and increasing the output power density by more than 30%.

Reliability and lifespan extension: The integrated structure enhances the interlayer bonding strength, reducing the probability of layer separation failure during thermal cycling by over 70%, and significantly extending the operational lifespan.

Promoting industrialization process: This technology reduces mold costs and material waste, and shortens the production cycle by approximately 40%. It provides a key technical solution for the low-cost and flexible mass production of fuel cells.

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We have a wide range of technologies such as material technology, process technology, design technology, measurement/evaluation technology, and integrated processes from materials to products in-house, so we can respond to various customizations. Please feel free to contact us first.
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